Direct growth of SnO2 nanorod array electrodes for lithium-ion batteries

被引:275
作者
Liu, Jinping [1 ]
Li, Yuanyuan [1 ]
Huang, Xintang [1 ,2 ]
Ding, Ruimin [1 ]
Hu, Yingying [1 ]
Jiang, Jian [1 ]
Liao, Lei [3 ]
机构
[1] Cent China Normal Univ, Dept Phys, Ctr Nanosci & Nanotechnol, Wuhan 430079, Peoples R China
[2] Hubei Univ, Key Lab Ferroelect & Piezoelect Mat & Devices Hub, Wuhan 430079, Peoples R China
[3] Wuhan Univ, Dept Phys, Wuhan 430072, Peoples R China
基金
中国国家自然科学基金;
关键词
HIGH-CAPACITY; ELECTROCHEMICAL PROPERTIES; NANOSTRUCTURED ELECTRODES; TEMPLATE SYNTHESIS; TIN-NANOPARTICLES; MESOPOROUS SNO2; NANOWIRE ARRAYS; CO3O4; NANOTUBES; ANODE MATERIALS; HOLLOW SPHERES;
D O I
10.1039/b817036c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SnO2 nanorod arrays have been prepared on large-area flexible metallic substrates (Fe-Co-Ni alloy and Ni foil) via a hydrothermal process for the first time and have been demonstrated as a high-performance anode material for lithium ion batteries. Electrochemical behavior is found to depend crucially on the structural parameters of the array. An array consisting of SnO2 nanorods of average 60 nm in diameter and 670 nm in length delivers a reversible capacity of as high as 580 mAh g(-1) after 100 cycles (at 0.1C) and shows excellent rate capability (350 mAh g(-1) at the 5C rate). Structural disintegration and agglomeration were not observed for SnO2 arrays even after 50 cycles.
引用
收藏
页码:1859 / 1864
页数:6
相关论文
共 65 条
  • [1] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [2] Building better batteries
    Armand, M.
    Tarascon, J. -M.
    [J]. NATURE, 2008, 451 (7179) : 652 - 657
  • [3] Thin-film crystalline SnO2-lithium electrodes
    Brousse, T
    Retoux, R
    Herterich, U
    Schleich, DM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (01) : 1 - 4
  • [4] Nanomaterials for rechargeable lithium batteries
    Bruce, Peter G.
    Scrosati, Bruno
    Tarascon, Jean-Marie
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) : 2930 - 2946
  • [5] High capacity Li ion battery anodes using Ge nanowires
    Chan, Candace K.
    Zhang, Xiao Feng
    Cui, Yi
    [J]. NANO LETTERS, 2008, 8 (01) : 307 - 309
  • [6] High-performance lithium battery anodes using silicon nanowires
    Chan, Candace K.
    Peng, Hailin
    Liu, Gao
    McIlwrath, Kevin
    Zhang, Xiao Feng
    Huggins, Robert A.
    Cui, Yi
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (01) : 31 - 35
  • [7] Chemical-vapor deposition-based template synthesis of microtubular TiS2 battery electrodes
    Che, G
    Jirage, KB
    Fisher, ER
    Martin, CR
    Yoneyama, H
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (12) : 4296 - 4302
  • [8] α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications
    Chen, J
    Xu, LN
    Li, WY
    Gou, XL
    [J]. ADVANCED MATERIALS, 2005, 17 (05) : 582 - +
  • [9] Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites
    Courtney, IA
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) : 2045 - 2052
  • [10] A one-step approach towards carbon-encapsulated hollow tin nanoparticles and their application in lithium batteries
    Cui, Guanglei
    Hu, Yong-Sheng
    Zhi, Linjie
    Wu, Dongqing
    Lieberwirth, Ingo
    Maier, Joachim
    Muellen, Klaus
    [J]. SMALL, 2007, 3 (12) : 2066 - 2069