Electrochemical oxidation of chlorinated benzenes

被引:10
作者
Jedral, W [1 ]
Merica, SG [1 ]
Bunce, NJ [1 ]
机构
[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
electrooxidation; chlorinated benzenes; voltammetry;
D O I
10.1016/S1388-2481(99)00020-X
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrochemical oxidation of benzene and its chloro derivatives (n=1-3) has been studied in acetonitrile, water, and an aqueous emulsion at both metallic electrodes and dimensionally stable anodes. In acetonitrile all substrates underwent a six-electron oxidation near + 3 V versus the standard hydrogen electrode. Low yields of organic products, principally phenols, were obtained; electrochemical combustion to CO2 was a major reaction pathway, but current efficiencies were low. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:108 / 110
页数:3
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