A flexible route to [4.1.1]propellanes

被引：1

作者：

AlDulayymi, AR

AlDulayymi, JR

Baird, MS

机构：

[1] Department of Chemistry, University of Wales, Bangor

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(97)01545-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of Diels-Alder adducts of 1-bromo-2-bromomethylclopropene and either 1,3-dienes or furans with butyl lithium leads to a 1,3-dehalogenation to produce [4.1.1]propellanes. The oxygen bridged propellane derived from furan reacts with a second mol.equiv. of butyllithium by cleavage of the bridge with allylic rearrangement and the formation of a cis-3-butyl-[4.1.1]propell-4-en-2-ol. (C) 1997 Elsevier Science Ltd.

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页码：6755 / 6758

页数：4

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