fac-Tris(tert-butyl isocyanide)tricarbonyl-molybdenum(0)

被引：6

作者：

Imhof, W ^{[1
]}

Halbauer, K ^{[1
]}

Dönnecke, D ^{[1
]}

Görls, H ^{[1
]}

机构：

[1] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806004181

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [ Mo( C5H9N) (3)( CO) (3)], was produced from Mo( CO) (6) and tert- butyl isocyanide in the presence of 10 atm of carbon monoxide ( 1 atm = 101325 Pa). The octahedral complex shows a facial arrangement of the ligands, the Mo - C distances of the isocyanide ligands being about 0.15 angstrom longer than the corresponding bond lengths of the carbonyl ligands. The crystal structure is influenced by one short C - H center dot center dot center dot center dot O contact, resulting in infinite chains which are interconnected by additional weak C - H center dot center dot center dot center dot O interactions.

引用

页码：M462 / M464

页数：3

共 13 条

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