Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties

被引:1272
作者
Sandler, J
Shaffer, MSP
Prasse, T
Bauhofer, W
Schulte, K
Windle, AH [1 ]
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] Tech Univ Hamburg, Mat Microelect Sect, D-21073 Hamburg, Germany
关键词
carbon nanotubes; epoxy matrix; electrical properties;
D O I
10.1016/S0032-3861(99)00166-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
To avoid electrostatic charging of an insulating matrix an electrical conductivity above sigma = 10(-6) Sm-1 is needed. At present, the most common practice to achieve this conductivity is to use a conductive filler such as carbon black. In this work, untreated catalytically-grown carbon nanotubes were dispersed in an epoxy matrix. After curing the epoxy, the electrical properties of the composite were measured in order to relate the filler volume fraction to the electrical conductivity. The intense stirring process used to disperse the carbon nanotubes has made it possible to achieve a matrix conductivity around sigma = 10(-2) Sm-1 with filler volume fractions as low as 0.1 vol.%. These figures represent an advance on best conductivity values previously obtained with carbon black in the same epoxy matrix. These low filler fractions ensure that the mechanical properties of the matrix are not compromised. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:5967 / 5971
页数:5
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