Exergy analysis of ammonia-based solar thermochemical power systems

被引:46
作者
Lovegrove, K [1 ]
Luzzi, A [1 ]
McCann, M [1 ]
Freitag, O [1 ]
机构
[1] Australian Natl Univ, Dept Engn, Ctr Sustainable Energy Syst, Canberra, ACT 0200, Australia
关键词
D O I
10.1016/S0038-092X(98)00132-7
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The reversible dissociation of ammonia is one of the candidate reactions for use in closed loop solar thermochemical energy storage systems. The major determinant of achievable performance for such a system is the degree of thermodynamic irreversibility associated with the heat recovery process. Exergy analysis of a semi realistic 30 MPa isobaric system has revealed that the major irreversibilities occur within the exothermic reactor and the counterflow heat exchanger between ingoing and outgoing reactants. In this study, optimum reactor control yielded exergetic efficiencies up to 71%, which should translate to overall solar to electric conversion efficiencies of around 20%. (C) 1999 Elsevier Science Ltd All rights reserved.
引用
收藏
页码:103 / 115
页数:13
相关论文
共 19 条
[1]  
BANNISTER P, 1991, THESIA AUSTR NATL U
[2]   CARBON-DIOXIDE REFORMING OF METHANE IN A SOLAR VOLUMETRIC RECEIVER REACTOR - THE CAESAR PROJECT [J].
BUCK, R ;
MUIR, JF ;
HOGAN, RE ;
SKOCYPEC, RD .
SOLAR ENERGY MATERIALS, 1991, 24 (1-4) :449-463
[3]   ENERGY CO-RADIATION USING REVERSIBLE AMMONIA REACTION [J].
CARDEN, PO .
SOLAR ENERGY, 1977, 19 (04) :365-378
[4]  
CARDEN PO, 1974, ECTR8 AUSTR NAT U DE
[5]   SOLAR TEST OF AN INTEGRATED SODIUM REFLUX HEAT PIPE RECEIVER REACTOR FOR THERMOCHEMICAL ENERGY-TRANSPORT [J].
DIVER, RB ;
FISH, JD ;
LEVITAN, R ;
LEVY, M ;
MEIROVITCH, E ;
ROSIN, H ;
PARIPATYADAR, SA ;
RICHARDSON, JT .
SOLAR ENERGY, 1992, 48 (01) :21-30
[6]  
LEVITAN R, 1989, SOLAR ENERGY MAT, V24, P464
[7]   SOLAR-ENERGY STORAGE VIA A CLOSED-LOOP CHEMICAL HEAT PIPE [J].
LEVY, M ;
LEVITAN, R ;
ROSIN, H ;
RUBIN, R .
SOLAR ENERGY, 1993, 50 (02) :179-189
[8]   Endothermic reactors for an ammonia based thermochemical solar energy storage and transport system [J].
Lovegrove, K ;
Luzzi, A .
SOLAR ENERGY, 1996, 56 (04) :361-371
[9]   THERMODYNAMIC LIMITS ON THE PERFORMANCE OF A SOLAR THERMOCHEMICAL ENERGY-STORAGE SYSTEM [J].
LOVEGROVE, K .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 1993, 17 (09) :817-829
[10]   EXERGETIC OPTIMIZATION OF A SOLAR THERMOCHEMICAL ENERGY-STORAGE SYSTEM SUBJECT TO REAL CONSTRAINTS [J].
LOVEGROVE, K .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 1993, 17 (09) :831-845