Electronic absorption spectra of size-selected hydrated electron clusters: (H2O)(n)(-), n=6-50

被引：189

作者：

Ayotte, P

Johnson, MA

机构：

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 106卷 / 02期

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D O I：

10.1063/1.473167

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report photodestruction spectra for the (H2O)(n)(-) clusters (n=6, 11, 15, 20, 25, 30, 35, 40, and 50) in the range 0.7-1.6 eV. The spectra are observed to strongly redshift and narrow with decreasing cluster size, with a concomitant increase in peak intensity. The maxima occur well below the vertical detachment energies for n>20 and almost exclusively result from excitation of a bound-bound transition. (C) 1997 American Institute of Physics.

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页码：811 / 814

页数：4

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