A 3D-diamond-like tetrazole-based Zn(II) coordination polymer: Crystal structure, nonlinear optical effect and luminescent property

被引：57

作者：

Chen, Qi-Yong ^{[1
,2
]}

Li, Yan ^{[1
,2
]}

Zheng, Fa-Kun ^{[1
]}

Zou, Wen-Qiang ^{[1
]}

Wu, Mei-Feng ^{[1
,2
]}

Guo, Guo-Cong ^{[1
]}

Wu, A-Qing ^{[1
]}

Huang, Jin-Shun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期

基金：

中国国家自然科学基金;

关键词：

coordination polymer; 1H-tetrazole-5-formic acid; crystal structure; diamond-like network;

D O I：

10.1016/j.inoche.2008.05.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A tetrazole-based Zn(II) coordination polymer, [Zn(tzf)(2)](n) 1(Htzf= 1H-tetrazole-5-formic acid), was synthesized by reaction of ZnCl2 and Htzf, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 features a 3D-diamond-like net formed by the linkage of Zn(II) atoms and tetrazole groups. The carboxylate O atoms in tzf ligand remain uncoordinated. Polymer 1 displays a second harmonic generation response, which is ca. 1.1 times that of KDP (KH2PO4). The photoluminescent analysis reveals that 1 exhibits strong blue emission resulting from intraligand charge transition. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：969 / 971

页数：3

共 26 条

[1] Self-Assembly of a CsCl-like 3D Supramolecular Network from [Zn6(HL)6(H2L)6]6+ Metallamacrocycles and (H2O)20 Clusters (H2L=4-(2-Pyridyl)-6-(4-pyri(tyl)-2-aminopyrimidine) [J].