Catalytic dimerization of acrylonitrile

被引：50

作者：

Kashiwagi, K

Sugise, R

Shimakawa, T

Matuura, T

Shirai, M

Kakiuchi, F

Murai, S

机构：

[1] UBE IND LTD,UBE,YAMAGUCHI 755,JAPAN

[2] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 11期

关键词：

D O I：

10.1021/om970263a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new catalytic system using the combination RuCl2(DMSO)(4)/CH3CH2COONa/DMSO/carboxylic acid which enables selective dimerization of acrylonitrile to linear dimers without formation of propionitrile as a byproduct has been developed on the basis of a new working hypothesis of the desirable reaction mechanism involving protonolysis of a C-Ru bond in the intermediate.

引用

页码：2233 / 2235

页数：3

共 42 条

[1] KINETICS AND MECHANISM OF CATALYSIS OF THE ASYMMETRIC HYDROGENATION OF ALPHA-BETA-UNSATURATED CARBOXYLIC-ACIDS BY BIS(CARBOXYLATO)(2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL)-RUTHENIUM(II), [RUII(BINAP)(O2CR)2] [J].