Solubility of fullerene C-60 and C-70 in toluene o-xylene and carbon disulfide at various temperatures

被引：69

作者：

Zhou, XH ^{[1
]}

Liu, JB ^{[1
]}

Jin, ZX ^{[1
]}

Gu, ZN ^{[1
]}

Wu, YQ ^{[1
]}

Sun, YL ^{[1
]}

机构：

[1] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1997年 / 5卷 / 01期

关键词：

D O I：

10.1080/15363839708011990

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solubilities of fullerene C-60 and C-70 in toluene, o-xylene and carbon disulfide between the melting point and boiling point of the solvents, respectively, have been measured. The temperature dependent solubility of C-60 displays anomalous behaviors. A solubility maximum of C-60 around 0 degrees C for toluene and carbon sulfide and around 30 degrees C for o-xylene was observed. The temperature-dependent solubility of C-70 behaves normally for all the three solvents studied.

引用

页码：285 / 290

页数：6

共 8 条

[1]

Beck M. T., 1995, RECENT ADV CHEM PHYS, P1510

[2] SOLUBILITY OF C-60 IN A VARIETY OF SOLVENTS [J].

RUOFF, RS ;

TSE, DS ;

MALHOTRA, R ;

LORENTS, DC .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (13) :3379-3383

[3] ANOMALOUS SOLUBILITY BEHAVIOR OF C60 [J].

RUOFF, RS ;

MALHOTRA, R ;

HUESTIS, DL ;

TSE, DS ;

LORENTS, DC .

NATURE, 1993, 362 (6416) :140-141

[4]

SERIVENS WA, 1993, J CHEM SOC CHEM COMM, P1207

[5] SOLUBILITY OF C-60 IN ORGANIC-SOLVENTS [J].

SIVARAMAN, N ;

DHAMODARAN, R ;

KALIAPPAN, I ;

SRINIVASAN, TG ;

RAO, PRV ;

MATHEWS, CK .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (22) :6077-6079

[6]

SIVARAMAN N, 1994, FULLERENE SCI TECHN, V2, P133

[7] ANALYSIS OF C-60 AND C-70 FULLERENES BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

WU, YQ ;

SUN, YL ;

GU, ZN ;

WANG, QW ;

ZHOU, XH ;

XIONG, Y ;

JIN, ZX .

JOURNAL OF CHROMATOGRAPHY, 1993, 648 (02) :491-496

[8]

ZHOU XH, 1994, CARBON, V32, P935

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