Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials

被引:142
作者
Batten, Robert D. [2 ]
Stillinger, Frank H. [1 ]
Torquato, Salvatore [1 ,3 ,4 ,5 ,6 ]
机构
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[2] Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA
[3] Princeton Univ, Princeton Inst Sci & Technol Mat, Princeton, NJ 08544 USA
[4] Princeton Univ, Program Appl & Computat Math, Princeton, NJ 08544 USA
[5] Princeton Univ, Princeton Ctr Theoret Sci, Princeton, NJ 08544 USA
[6] Princeton Univ Sch Nat Sci, Inst Adv Study, Princeton, NJ 08544 USA
关键词
D O I
10.1063/1.2961314
中图分类号
O59 [应用物理学];
学科分类号
摘要
Using a collective coordinate numerical optimization procedure, we construct ground-state configurations of interacting particle systems in various space dimensions so that the scattering of radiation exactly matches a prescribed pattern for a set of wave vectors. We show that the constructed ground states are, counterintuitively, disordered (i.e., possess no long-range order) in the infinite-volume limit. We focus on three classes of configurations with unique radiation scattering characteristics: (i) "stealth" materials, which are transparent to incident radiation at certain wavelengths; (ii) "super-ideal" gases, which scatter radiation identically to that of an ensemble of ideal gas configurations for a selected set of wave vectors; and (iii) "equi-luminous" materials, which scatter radiation equally intensely for a selected set of wave vectors. We find that ground-state configurations have an increased tendency to contain clusters of particles as one increases the prescribed luminosity. Limitations and consequences of this procedure are detailed. (C) 2008 American Institute of Physics.
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页数:12
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