Ruddlesden-Popper-Type Epitaxial Film as Oxygen Electrode for Solid-Oxide Fuel Cells

被引：46

作者：

Yamada, Atsuo ^{[1
]}

Suzuki, Yoshitaka ^{[1
]}

Saka, Kazuyuki ^{[1
]}

Uehara, Makiko ^{[1
]}

Mori, Daisuke ^{[1
]}

Kanno, Ryoji ^{[1
]}

Kiguchi, Takanori ^{[2
]}

Mauvy, Fabrice ^{[3
]}

Grenier, Jean-Claude ^{[3
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

[2] Tokyo Inst Technol, Ctr Adv Mat Anal, Meguro Ku, Tokyo 1528550, Japan

[3] CNRS, ICMCB, Pessac, France

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 21期

关键词：

D O I：

10.1002/adma.200801199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unexpected SOFC hetero-epitaxial system with large lattice mismatch is demonstrated. A (110)-oriented flat epitaxial film of Nd2NiO4+delta is successfully grown on the (100) surface of yttrium-stabilized zirconia, which realizes selective exposure of the active surface for oxygen reduction. The charge-transfer process is analyzed to be the rate-limiting step with a simple impedance model.

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页码：4124 / +

页数：6

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