Schottky Solar Cells Based on Colloidal Nanocrystal Films

被引：818

作者：

Luther, Joseph M. ^{[1
,2
]}

Law, Matt ^{[1
]}

Beard, Matthew C. ^{[1
]}

Song, Qing ^{[1
]}

Reese, Matthew O. ^{[1
]}

Ellingson, Randy J. ^{[1
]}

Nozik, Arthur J. ^{[1
]}

机构：

[1] Natl Renewable Energy Lab, Golden, CO 80401 USA

[2] Colorado Sch Mines, Dept Phys, Golden, CO 80401 USA

来源：

NANO LETTERS | 2008年 / 8卷 / 10期

关键词：

D O I：

10.1021/nl802476m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe here a simple, all-inorganic metal/NC/metal sandwich photovoltaic (PV) cell that produces an exceptionally large short-circuit photocurrent (>21 mA cm(-2)) by way of a Schottky junction at the negative electrode. The PV cell consists of a PbSe NC film, deposited via layer-by-layer (LbL) dip coating that yields an EQE of 55-65% in the visible and up to 25% in the infrared region of the solar spectrum, with a spectrally corrected AM1.5G power conversion efficiency of 2.1%. This NC device produces one of the largest short-circuit currents of any nanostructured solar cell, without the need for sintering, superlattice order or separate phases for electron and hole transport.

引用

页码：3488 / 3492

页数：5

共 35 条

[1] Multiple exciton generation in colloidal silicon nanocrystals
Beard, Matthew C.
Knutsen, Kelly P.
Yu, Pingrong
Luther, Joseph M.
Song, Qing
Metzger, Wyatt K.
Ellingson, Randy J.
Nozik, Arthur J.
[J]. NANO LETTERS, 2007, 7 (08) : 2506 - 2512
[2] BEARD MC, 2008, UNPUB
[3] Schottky barriers to colloidal quantum dot films
Clifford, Jason P.
Johnston, Keith W.
Levina, Larissa
Sargent, Edward H.
[J]. APPLIED PHYSICS LETTERS, 2007, 91 (25)
[4] Harvest of near infrared light in PbSe nanocrystal-polymer hybrid photovoltaic cells
Cui, DH
Xu, J
Zhu, T
Paradee, G
Ashok, S
Gerhold, M
[J]. APPLIED PHYSICS LETTERS, 2006, 88 (18)
[5] A PbS nanocrystal-C60 photovoltaic device for infrared light harvesting
Dissanayake, D. M. N. M.
Hatton, Ross A.
Lutz, Thierry
Giusca, Cristina E.
Curry, Richard J.
Silva, S. R. P.
[J]. APPLIED PHYSICS LETTERS, 2007, 91 (13)
[6] Highly efficient multiple exciton generation in colloidal PbSe and PbS quantum dots
Ellingson, RJ
Beard, MC
Johnson, JC
Yu, PR
Micic, OI
Nozik, AJ
Shabaev, A
Efros, AL
[J]. NANO LETTERS, 2005, 5 (05) : 865 - 871
[7] IV-VI nanocrystal-polymer solar cells
Fritz, Karolina P.
Guenes, Serap
Luther, Joseph
Kumar, Sandeep
Saricifitci, N. Serdar
Scholes, Gregory D.
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 195 (01) : 39 - 46
[8] Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells
Grätzel, M
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) : 3 - 14
[9] VERIFICATION OF HIGH EFFICIENCIES FOR THE GRATZEL-CELL - A 7-PERCENT EFFICIENT SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS
HAGFELDT, A
DIDRIKSSON, B
PALMQVIST, T
LINDSTROM, H
SODERGREN, S
RENSMO, H
LINDQUIST, SE
[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1994, 31 (04) : 481 - 488
[10] PHOTOCONDUCTION IN POROUS TIO2 SENSITIZED BY PBS QUANTUM DOTS
HOYER, P
KONENKAMP, R
[J]. APPLIED PHYSICS LETTERS, 1995, 66 (03) : 349 - 351

← 1 2 3 4 →