Synthesis of Poly(paraphenylene vinylene)-Polystyrene-Based Rod-Coil Block Copolymer by Atom Transfer Radical Polymerization: Toward a Self-Organized Lamellar Semiconducting Material

被引：21

作者：

Brochon, Cyril ^{[1
]}

Sary, Nicolas ^{[2
,3
]}

Mezzenga, Raffaele ^{[2
,3
,4
]}

Ngov, Chheng ^{[1
]}

Richard, Fanny ^{[1
]}

May, Michael ^{[1
]}

Hadziioannou, Georges ^{[1
]}

机构：

[1] Univ Strasbourg, Ecole Europeenne Chim Polymeres & Mat, Lab Ingn Polymeres Hautes Technol, UMR 7165, F-67000 Strasbourg, France

[2] Univ Fribourg, Dept Phys, CH-1700 Fribourg, Switzerland

[3] Univ Fribourg, Fribourg Ctr Nanomat, CH-1700 Fribourg, Switzerland

[4] Nestle Res Ctr, CH-1000 Lausanne 26, Switzerland

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2008年 / 110卷 / 06期

关键词：

PPV; semiconducting polymer; ATRP; rod-coil block copolymer; self-assembly; photovoltaic polymer materials;

D O I：

10.1002/app.28960

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Atom transfer radical polymerization (ATRP) was used as a versatile route to well-defined poly(diethyl-hexyl-p-phenylenevinylene-b-styrene) (PPV-b-PS) semiconducting block copolymers. For this purpose, original conjugated macroinitiators were synthesized from DEH-PPV and further used for the copolymerization reaction. The microphase-separated morphologies obtained with the semiconducting PPV-b-PS block copolymer fulfill the basic structural requirements required to build efficient organic photovoltaic devices. (c) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 3664-3670, 2008

引用

页码：3664 / 3670

页数：7

共 36 条

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