Shaping the cavity of calix[4]arene using transition metals and binding alkali-metal cations inside the cavity: The relevance of the alkali-metal cation-arene interaction

被引：50

作者：

ZanottiGerosa, A

Solari, E

Giannini, L

Floriani, C

ChiesiVilla, A

Rizzoli, C

机构：

[1] UNIV LAUSANNE,BCH,INST CHIM MINERALE & ANALYT,CH-1015 LAUSANNE,SWITZERLAND

[2] UNIV PARMA,DIPARTIMENTO CHIM,I-43100 PARMA,ITALY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a606826j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metals can be used for shaping and electronically enriching the calix[4]arene cavity; in this approach, the pi-basic cavities can be adapted to alkali-metal cation complexation in a very hydrophobic environment and these cations can even be transferred into aliphatic hydrocarbons; the eta(6)-arene-alkali-metal cation interaction is structurally elucidated.

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页码：183 / 184

页数：2

相关论文

共 30 条

[1] PENTAMETHYLCYCLOPENTADIENYL AND CYCLOPENTADIENYL TANTALUM AND NIOBIUM CALIXARENE COMPOUNDS AND THEIR WATER AND ACETONITRILE INCLUSION COMPLEXES [J].

ACHO, JA ;

DOERRER, LH ;

LIPPARD, SJ .

INORGANIC CHEMISTRY, 1995, 34 (10) :2542-2556

[2] DIMOLYBDENUM(II) CALIXARENE COMPLEXES - SYNTHESIS, STRUCTURE, RAMAN-SPECTROSCOPY, AND BONDING [J].

ACHO, JA ;

REN, T ;

YUN, JW ;

LIPPARD, SJ .

INORGANIC CHEMISTRY, 1995, 34 (21) :5226-5233

[3] THE PREPARATION AND PROPERTIES OF A NEW LIPOPHILIC SODIUM SELECTIVE ETHER ESTER LIGAND DERIVED FROM PARA-TERT-BUTYLCALIX(4)ARENE [J].

ARDUINI, A ;

POCHINI, A ;

REVERBERI, S ;

UNGARO, R ;

ANDREETTI, GD ;

UGOZZOLI, F .

TETRAHEDRON, 1986, 42 (07) :2089-2100

[4] MOLECULAR INCLUSION IN FUNCTIONALIZED MACROMOLECULES .15. PARA-TERT-BUTYLCALIX[4]ARENE TETRA-ACETAMIDE - A NEW STRONG RECEPTOR FOR ALKALI CATIONS [J].

ARDUINI, A ;

GHIDINI, E ;

POCHINI, A ;

UNGARO, R ;

ANDREETTI, GD ;

CALESTANI, G ;

UGOZZOLI, F .

JOURNAL OF INCLUSION PHENOMENA, 1988, 6 (02) :119-134

[5]

ARNAUDNEU F, 1991, NEW J CHEM, V15, P33

[6] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .5. PROTONATION CONSTANTS FOR CALIXARENE CARBOXYLATES AND STABILITY-CONSTANTS OF THEIR ALKALI AND ALKALINE-EARTH COMPLEXES [J].

ARNAUDNEU, F ;

BARRETT, G ;

HARRIS, SJ ;

OWENS, M ;

MCKERVEY, MA ;

SCHWINGWEILL, MJ ;

SCHWINTE, P .

INORGANIC CHEMISTRY, 1993, 32 (12) :2644-2650

[7] SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CATION-BINDING PROPERTIES OF ALKYL CALIXARYL ESTERS AND KETONES, A NEW FAMILY OF MACROCYCLIC MOLECULAR RECEPTORS [J].

ARNAUDNEU, F ;

COLLINS, EM ;

DEASY, M ;

FERGUSON, G ;

HARRIS, SJ ;

KAITNER, B ;

LOUGH, AJ ;

MCKERVEY, MA ;

MARQUES, E ;

RUHL, BL ;

SCHWINGWEILL, MJ ;

SEWARD, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) :8681-8691

[8] CATION COMPLEXATION BY CHEMICALLY-MODIFIED CALIXARENES .7. TRANSPORT OF ALKALI CATIONS BY P-TERT-BUTYLCALIX[N]ARENE ESTERS AND AMIDES [J].

ARNAUDNEU, F ;

FANNI, S ;

GUERRA, L ;

MCGREGOR, W ;

ZIAT, K ;

SCHWINGWEILL, MJ ;

BARRETT, G ;

MCKERVEY, MA ;

MARRS, D ;

SEWARD, EM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (01) :113-118

[9] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND CATION BINDING-PROPERTIES OF A TETRAHOMODIOXACALIX[4]ARENE TETRAESTER [J].

ARNAUDNEU, F ;

CREMIN, S ;

CUNNINGHAM, D ;

HARRIS, SJ ;

MCARDLE, P ;

MCKERVEY, MA ;

MCMANUS, M ;

SCHWINGWEILL, MJ ;

ZIAT, K .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 10 (03) :329-339

[10] ALKALI-METAL ION COMPLEXES OF THE CALIXARENES .1. CESIUM BONDING IN CALIX[4]ARENE SYSTEMS [J].

ASSMUS, R ;

BOHMER, V ;

HARROWFIELD, JM ;

OGDEN, MI ;

RICHMOND, WR ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16) :2427-2433