Dynamic kinetic resolution with enzyme and palladium combinations

被引：156

作者：

Allen, JV ^{[1
]}

Williams, JMJ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 11期

关键词：

D O I：

10.1016/0040-4039(96)00136-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dynamic kinetic resolution of certain allyl acetates has been achieved by enzymatic hydrolysis to the corresponding allyl alcohols. In the presence of a palladium catalyst, the allyl acetate is racemised, allowing a dynamic resolution to take place.

引用

页码：1859 / 1862

页数：4

共 10 条

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