Reactions of orthomanganated aryl ketones with PhNSO and related species: A new route to orthomanganated imines

被引：9

作者：

Cooney, JM ^{[1
]}

Main, L ^{[1
]}

Nicholson, BK ^{[1
]}

机构：

[1] UNIV WAIKATO,SCH SCI & TECHNOL,HAMILTON,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 516卷 / 1-2期

关键词：

manganese; carbonyl; orthometallation; imines; crystal structure;

D O I：

10.1016/0022-328X(95)06082-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

PhN=S=O reacts with some orthomanganated acetophenones to replace the ketone oxygen with a Ph-N group, so generating the corresponding orthomanganated imine. No insertion into the Mn-C bond was observed, in contrast to analogous reactions of SO2. The related PhS(O)(2)N=S=O or (PhS(O)(2)N=)(2)S did not react under the same conditions. The X-ray crystal structure of one of the new imine complexes, eta(2)-3-chloro-2-[1-(N-phenylimino)ethyl]phenyltetracarbonylmanganese, was determined.

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收藏

页码：191 / 197

页数：7

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