Synthesis of (+)-8-deoxyvernolepin

被引:11
作者
Astudillo, L
Gonzalez, AG
Galindo, A
Mansilla, H
机构
[1] UNIV LA LAGUNA,INST UNIV BIOORGAN,LA LAGUNA 38206,TENERIFE,SPAIN
[2] CSIC,INST PROD NAT & AGROBIOL,LA LAGUNA 38206,TENERIFE,SPAIN
关键词
D O I
10.1016/S0040-4039(97)01540-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of (+)-8-deoxyvernolepin 1b was accomplished by a short and efficient route from arsantin 5. The key step involves a drastic rearrangement of an iodomesylate intermediate 4a by the action of zinc. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:6737 / 6740
页数:4
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