Non-natural eight-connected solid-state materials:: A new coordination chemistry

被引：173

作者：

Long, DL

Hill, RJ

Blake, AJ

Champness, NR

Hubberstey, P

Proserpio, DM

Wilson, C

Schröder, M

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 14期

关键词：

coordination modes; crystal engineering; lanthanides; supramolecular chemistry;

D O I：

10.1002/anie.200352625

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Non-CsCI topologies for eight-connected solid-state materials have been observed for the first time in three networks based on lanthanide cations and 4,4′-bipyridine-N,N′-dioxide ligands. The structure of the {[Yb(L)4](CF3SO3)3} ∞ network is depicted.

引用

页码：1851 / 1854

页数：4

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