Synthesis and crystal structure of a calix[4]arene-based dual boron-dipyrrin system.

被引：7

作者：

Nishioka, T ^{[1
]}

Arimura, T ^{[1
]}

Suga, Y ^{[1
]}

Murata, S ^{[1
]}

Tachiya, M ^{[1
]}

Goto, M ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 12期

关键词：

D O I：

10.1246/bcsj.74.2435

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of a calix[4]arene-based dual boron-dipyrrin system was accomplished by the condensation of diformylcalix[4]arene and pyrrole followed by a treatment with DDQ and diethyl ether-boron trifluoride (1/1). An X-ray crystal structure analysis and spectroscopic measurements revealed that the cone conformation of calix[4]arene serves to define 14.9 (A) over circle as the center-to-center boron-dipyrrin separation.

引用

页码：2435 / 2436

页数：2

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