Amination of 1-octanol

被引：21

作者：

Dume, C ^{[1
]}

Hölderich, WF ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Dept Chem Technol & Heterogeneous Catalysis, D-52074 Aachen, Germany

来源：

APPLIED CATALYSIS A-GENERAL | 1999年 / 183卷 / 01期

关键词：

amination; 1-octylamine; zeolites; metal phosphates; metal oxides;

D O I：

10.1016/S0926-860X(99)00054-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In amination of 1-octanol the opportunity to get directly the amine via a nucleophilic substitution reaction over metal phosphate catalysts (i.e. zirconium, cerium or boron phosphates), or zeolites has been investigated. Thereby, the dehydration of octanol is in competition with the amination. In comparison the reductive amination on copper chromite and nickel oxide on silica or alumina as carrier was checked, too. Thereby, complete conversion, as well as almost 100% selectivity to a mixture of 1-octylamine and octane nitrile are achieved. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：167 / 176

页数：10

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