Combinatorial catalysis with bimetallic complexes: Robust and efficient catalysts for atom-transfer radical additions

被引：92

作者：

Quebatte, L ^{[1
]}

Scopelliti, R ^{[1
]}

Severin, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 12期

关键词：

combinatorial chemistry; heterogeneous catalysis; Kharasch reaction; rhodium; ruthenium;

D O I：

10.1002/anie.200353084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A radical alternative? Two highly efficient catalysts for atom-transfer radical additions were discovered in a parallel screening of bimetallic complexes. Both catalysts contain a rhodium-centered fragment (blue), which is connected through three chloro bridges to a ruthenium-centered fragment (red).

引用

页码：1520 / 1524

页数：5

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