Stereospecific formation of R-aromatic acyloins by Zymomonas mobilis pyruvate decarboxylase

被引:19
作者
Bornemann, S
Crout, DHG
Dalton, H
Kren, V
Lobell, M
Dean, G
Thomson, N
Turner, MM
机构
[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
[2] UNIV WARWICK,DEPT BIOL SCI,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 05期
关键词
D O I
10.1039/p19960000425
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recombinant pyruvate decarboxylase from Zymomonas mobilis catalysed the formation of R-aromatic acyloins of high optical purity from aromatic aldehydes and either pyruvate or acetaldehyde. The results are contrasted with those obtained with aliphatic acyloins and compared with those obtained with the pyruvate decarboxylase of Saccharomyces sp.
引用
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页码:425 / 430
页数:6
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