Sequence length distributions (microstructure) of regioregular poly(3-alkylthiophene)s and related conjugated polymers and their use in simulating π-π* absorption peak profiles

被引：17

作者：

Curtis, MD ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Ctr Macromol Sci & Engn, Ann Arbor, MI 48109 USA

来源：

MACROMOLECULES | 2001年 / 34卷 / 22期

关键词：

D O I：

10.1021/ma011053j

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The head-tail (HT) sequence length distributions (SLDs) of poly(3-alkylthiophenes) (P3ATs) and related polymers may be obtained from the H NMR spectra. The results show that the regioregular polymers, i.e., those with the highest HT content, have broader SLDs than the less regular polymers. The SLD may be used to simulate the characteristic profiles of the pi-pi* absorption peaks of P3ATs and related polymers.

引用

页码：7905 / 7910

页数：6

共 57 条

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