Conformational inversion processes in phytic acid: NMR spectroscopic and molecular modeling studies

被引：43

作者：

Bauman, AT ^{[1
]}

Chateauneuf, GM ^{[1
]}

Boyd, BR ^{[1
]}

Brown, RE ^{[1
]}

Murthy, PPN ^{[1
]}

机构：

[1] Michigan Technol Univ, Dept Chem, Houghton, MI 49931 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(99)00816-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NMR spectroscopy and computational studies show that phytic acid undergoes pH- and ion-dependent conformational inversion from the 1ax/5eq form to the 5ax/1eq form. The kinetics and energetics of the conformational inversion process are discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4489 / 4492

页数：4

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