Directing the structure of metal-organic frameworks by oriented surface growth on an organic monolayer

被引：178

作者：

Scherb, Camilla ^{[1
]}

Schoedel, Alexander ^{[1
]}

Bein, Thomas ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 31期

关键词：

crystal growth; iron; microporous materials; monolayers; surface chemistry;

D O I：

10.1002/anie.200704034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Orientation and structure of porous metal-organic frameworks (MOFs) based on iron and 1,4-benzenedicarboxylic acid can be controlled by heterogeneous nucleation on self-assembled monolayers of mercaptohexadecanoic acid (MHDA). Thus, the product of homogeneous nucleation is the MOF Fe-MIL-53, whereas in the same crystallization solution, oriented Fe-MIL-88B grows on a MHDA-functionalized gold surface (see picture). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5777 / 5779

页数：3

共 29 条

[1] CONTROL AND DESIGN PRINCIPLES IN BIOLOGICAL MINERALIZATION [J].

ADDADI, L ;

WEINER, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (02) :153-169

[2] Taking advantage of disorder: Amorphous calcium carbonate and its roles in biomineralization [J].

Addadi, L ;

Raz, S ;

Weiner, S .

ADVANCED MATERIALS, 2003, 15 (12) :959-970

[3]

Addadi L., 1992, ANGEW CHEM, V104, P159

[4] Crystallization in patterns: A bio-inspired approach [J].

Aizenberg, J .

ADVANCED MATERIALS, 2004, 16 (15) :1295-1302

[5] Oriented growth of calcite controlled by self-assembled monolayers of functionalized alkanethiols supported on gold and silver [J].

Aizenberg, J ;

Black, AJ ;

Whitesides, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4500-4509

[6] Preparation, modification, and crystallinity of aliphatic and aromatic carboxylic acid terminated self-assembled monolayers [J].

Arnold, R ;

Azzam, W ;

Terfort, A ;

Wöll, C .

LANGMUIR, 2002, 18 (10) :3980-3992

[7] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[8] CERAMIC THIN-FILM FORMATION ON FUNCTIONALIZED INTERFACES THROUGH BIOMIMETIC PROCESSING [J].

BUNKER, BC ;

RIEKE, PC ;

TARASEVICH, BJ ;

CAMPBELL, AA ;

FRYXELL, GE ;

GRAFF, GL ;

SONG, L ;

LIU, J ;

VIRDEN, JW ;

MCVAY, GL .

SCIENCE, 1994, 264 (5155) :48-55

[9] Structural diversity and chemical trends in hybrid inorganic-organic framework materials [J].

Cheetham, Anthony K. ;

Rao, C. N. R. ;

Feller, Russell K. .

CHEMICAL COMMUNICATIONS, 2006, (46) :4780-4795

[10] SYNTHESIS, STRUCTURE, AND PROPERTIES OF MODEL ORGANIC-SURFACES [J].

DUBOIS, LH ;

NUZZO, RG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 :437-463

← 1 2 3 →