Permanent blockade of in situ-generated acid Bronsted sites of vanadyl pyrophosphate catalysts by pyridine during the partial oxidation of toluene

被引：24

作者：

Martin, A ^{[1
]}

Bentrup, U ^{[1
]}

Lücke, B ^{[1
]}

Brückner, A ^{[1
]}

机构：

[1] Inst Angew Chem Berlin Adlershof eV, D-12484 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a902700i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The permanent blockade of in situ-formed Bronsted-acid OH groups and an effective lowering of the catalyst acidity during the partial oxidation of toluene to benzaldehyde is demonstrated by an efficient method using a continuous dosing of pyridine to the feed that leads to drastically increased aldehyde selectivities.

引用

页码：1169 / 1170

页数：2

共 10 条

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