Infrared chemiluminescence from the NO+HCO reaction: Observation of the 2 nu(1)-nu(1) hot band of HNO

被引：20

作者：

Butkovskaya, NI ^{[1
]}

Muravyov, AA ^{[1
]}

Setser, DW ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW 117334,RUSSIA

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 266卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(96)01540-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared chemiluminescence in the 2200-3000 cm(-1) range was observed from vibrationally excited HNO molecules produced in the reaction of NO with HCO. Formyl radicals were obtained from the OH + CH2O reaction in a fast-flow reactor connected with a Fourier transform spectrometer. The HNO spectrum consists of Delta nu(1) = -1 transitions from the (1 nu(2) nu(3)) and (200) levels. The anharmonicity coefficient x(11) = -116+/-1 cm(-1) was obtained from the position of the center of the (002)-(001) hot band, nu(0) = 2452 cm(-1).

引用

页码：223 / 226

页数：4

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