A silicon-tethered allenic Pauson-Khand reaction

被引:38
作者
Brummond, KM [1 ]
Sill, PC
Rickards, B
Geib, SJ
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15206 USA
[2] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4039(02)00633-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This manuscript describes a silicon-tethered Pauson-Khand reaction and subsequent cleavage of the resulting vinyl silane to afford functionalized alkylidene cyclopentenones. Altering the reaction conditions affords a selective reaction with either pi-bond of the allene. (C) 2002 Published by Elsevier Science Ltd.
引用
收藏
页码:3735 / 3738
页数:4
相关论文
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