A silicon-tethered allenic Pauson-Khand reaction

被引：38

作者：

Brummond, KM ^{[1
]}

Sill, PC

Rickards, B

Geib, SJ

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15206 USA

[2] W Virginia Univ, Dept Chem, Morgantown, WV 26506 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 20期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)00633-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This manuscript describes a silicon-tethered Pauson-Khand reaction and subsequent cleavage of the resulting vinyl silane to afford functionalized alkylidene cyclopentenones. Altering the reaction conditions affords a selective reaction with either pi-bond of the allene. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：3735 / 3738

页数：4

共 34 条

[1] BOIS M, 1995, CHEM REV, V95, P1253
[2] Recent advances in the Pauson-Khand reaction and related [2+2+1] cycloadditions
Brummond, KM
Kent, JL
[J]. TETRAHEDRON, 2000, 56 (21) : 3263 - 3283
[3] An intramolecular allenic [2+2+1]cycloaddition
Brummond, KM
Wan, HH
Kent, JL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (19) : 6535 - 6545
[4] The allenic Pauson-Khand cycloaddition.: Dependence in π-bond selectivity on substrate structure.
Brummond, KM
Wan, H
[J]. TETRAHEDRON LETTERS, 1998, 39 (09) : 931 - 934
[5] Brummond KM, 1999, ADV CYCLOAD, V6, P211
[6] Chung YK, 1999, COORDIN CHEM REV, V188, P297
[7] Fensterbank L, 1997, SYNTHESIS-STUTTGART, P813
[8] Ford JG, 2000, SYNLETT, P1415
[9] GEIS O, 1998, ANGEW CHEM, V110, P955, DOI DOI 10.1002/(SICI)1521-3757(19980403)110:7955::AID-9
[10] The asymmetric Pauson-Khand reaction. A review
Ingate, ST
Marco-Contelles, J
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1998, 30 (02) : 121 - +

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