A heterofulvene-like germylene with a betain reactivity

被引：151

作者：

Driess, Matthias ^{[1
]}

Yao, Shenglai ^{[1
]}

Brym, Markus ^{[1
]}

van Wuellen, Christoph ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem Metalorgan & Inorgan Mat, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 26期

关键词：

betains; C-C coupling; fulvenes; germylenes; heteroarenes;

D O I：

10.1002/anie.200600237

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electronic chameleon: The planar cyclogermylene 1 can be described by the resonance structures 1A and 1B. It is accessible in 79% yield by dehydrohalogenation of the corresponding (β-diketiminato)chlorogermylene by LiN(SiMe3)2. Although the contribution of the dipolar resonance structure 1A is relatively small, its influence is seen in the transformations of 1 with Me3SiOTf or 1,2-dibromoethane. R = 2,6-diisopropylphenyl. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4349 / 4352

页数：4

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