Studies on the synthesis of ETS-10 .2. Use of organic templates

被引：38

作者：

Das, TK ^{[1
]}

Chandwadkar, AJ ^{[1
]}

Budhkar, AP ^{[1
]}

Sivasanker, S ^{[1
]}

机构：

[1] NATL CHEM LAB,POONA 411008,MAHARASHTRA,INDIA

来源：

MICROPOROUS MATERIALS | 1996年 / 5卷 / 06期

关键词：

ETS-10; titanosilicate; synthesis of; synthesis using templates; choline chloride; hexaethyl diquat-5;

D O I：

10.1016/0927-6513(95)00075-5

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

ETS-10 has been synthesized using titanosilicate gels and organic templating agents such as choline chloride [OHCH2CH2(CH3)(3)N+Cl-] and the bromide salt of hexaethyl diquat-5 [Br-(C2H5N+(CH2N+(C2H5Br-]. The influences of temperature and concentration of the ingredients on the kinetics of synthesis are reported. Physicochemical characterizations of the samples have been carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared (IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and differential thermogravimetric analysis (DTA)/thermogravimetric analysis (TGA), and adsorption of water, n-hexane and mesitylene. The catalytic activities of H-ETS-10 in the dehydration of n-butanol and in the isomerization of m-xylene and 1,3,5-trimethylbenzene are reported.

引用

页码：401 / 410

页数：10

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