Palladium-catalyzed hydroxycarbonylation of aryl and vinyl triflates by in situ generated carbon monoxide under microwave irradiation

被引：24

作者：

Lesma, G

Sacchetti, A

Silvani, A

机构：

[1] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

[2] Univ Milan, CISI, I-20133 Milan, Italy

来源：

SYNTHESIS-STUTTGART | 2006年 / 04期

关键词：

carbonylations; carboxylic acids; microwaves; molybdenum hexacarbonyl; triflates;

D O I：

10.1055/s-2005-926288

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An operationally simple hydroxycarbonylation of aryl and vinyl triflates to the corresponding carboxylic acids with a palladium-mediated microwave system was carried out in water.

引用

页码：594 / 596

页数：3

共 31 条

[1]

[Anonymous], 1996, PALLADIUM REAGENTS C

[2] A highly selective aerobic oxidation process catalyzed by electron-deficient nitroarenes via single electron transfer processes [J].

Bjorsvik, HR ;

Liguori, L ;

Merinero, JAV .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (21) :7493-7500

[3] Palladium-catalyzed hydroxycarbonylation of aryl and vinyl halides or triflates by acetic anhydride and formate anions [J].

Cacchi, S ;

Fabrizi, G ;

Goggiamani, A .

ORGANIC LETTERS, 2003, 5 (23) :4269-4272

[4] SUBSTITUTION-REACTIONS OF CIS-BIS(2,2-'-BIPYRIDINE)DICARBONYL(SOLVENT)-MOLYBDENUM(II) AND CIS-BIS(2,2-'-BIPYRIDINE)DICARBONYLTUNGSTEN(II) SALTS WITH UNI-DENTATE, BI-DENTATE, AND TER-DENTATE TERTIARY PHOSPHINES, TRIMETHYL PHOSPHITE, NITRIC-OXIDE, AND 2,2-'-BIPYRIDINE [J].

CONNOR, JA ;

JAMES, EJ ;

OVERTON, C ;

WALSHE, JMA ;

HEAD, RA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (03) :511-515

[5] Efficient and selective aerobic oxidation of alcohols into aldehydes and ketones using ruthenium/TEMPO as the catalytic system [J].

Dijksman, A ;

Marino-González, A ;

Payeras, AMI ;

Arends, IWCE ;

Sheldon, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (28) :6826-6833

[6] PALLADIUM-CATALYZED CARBONYLATIVE COUPLING OF ARYL TRIFLATES WITH ORGANOSTANNANES [J].

ECHAVARREN, AM ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) :1557-1565

[7] PALLADIUM-CATALYZED COUPLING OF ARYL TRIFLATES WITH ORGANOSTANNANES [J].

ECHAVARREN, AM ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (18) :5478-5486

[8] Conformation and steric effects in mono- and dimethoxybenzoic acids [J].

Exner, O ;

Fiedler, P ;

Budesínsky, M ;

Kulhánek, J .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (10) :3513-3518

[9] Rapid palladium-catalyzed synthesis of esters from aryl halides utilizing Mo(CO)6 as a solid carbon monoxide source [J].

Georgsson, J ;

Hallberg, A ;

Larhed, M .

JOURNAL OF COMBINATORIAL CHEMISTRY, 2003, 5 (04) :350-352

[10] Phase-vanishing methodology for efficient bromination, alkylation, epoxidation, and oxidation reactions of organic substrates [J].

Jana, NK ;

Verkade, JG .

ORGANIC LETTERS, 2003, 5 (21) :3787-3790

← 1 2 3 4 →