Rapid synthesis of high-quality InP nanocrystals

被引：151

作者：

Xu, S ^{[1
]}

Kumar, S ^{[1
]}

Nann, T ^{[1
]}

机构：

[1] Univ Freiburg, Freiburg Mat Res Ctr, D-79104 Freiburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 04期

关键词：

D O I：

10.1021/ja057676k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rapid new method for preparation of monodisperse InP-nanocrystals was developed. A highly reactive indium precursor and tris(trimethylsilyl)phosphine (TMS)3P was reacted within a weakly coordinating solvent in the presence of a supporting protic agent. The yielded InP-nanocrystals had a very narrow size distribution without any size selection process. The precursor and ligand effects were considered as critical factors in control of nucleation and crystal growth process. Different ligands were introduced to study the reaction mechanism. The new method not only yielded the "best" InP-nanocrystals so far, but also includes the potential for preparation within a continuous flow reactor, because the utilized ester is liquid at room temperature. Copyright © 2006 American Chemical Society.

引用

页码：1054 / 1055

页数：2

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