Palladium catalysed copolymerisation of ethene with alkylacrylates:: polar comonomer built into the linear polymer chain

被引：413

作者：

Drent, E ^{[1
]}

van Dijk, R ^{[1
]}

van Ginkel, R ^{[1
]}

van Oort, B ^{[1
]}

Pugh, RI ^{[1
]}

机构：

[1] Shell Res & Technol Ctr, NL-1031 CM Amsterdam, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b111252j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copolymerisation of ethene and alkylacrylates is catalysed by palladium modified with di( 2- methoxyphenyl) phosphinobenzene- 2- sulfonic acid (DOPPBS); a linear polymer is produced in which acrylate units are incorporated into the polyethylene backbone.

引用

页码：744 / 745

页数：2

共 14 条

[1] Copolymerization of polar monomers with olefins using transition-metal complexes [J].

Boffa, LS ;

Novak, BM .

CHEMICAL REVIEWS, 2000, 100 (04) :1479-1493

[2]

Britovsek GJP, 1999, ANGEW CHEM INT EDIT, V38, P428, DOI 10.1002/(SICI)1521-3773(19990215)38:4<428::AID-ANIE428>3.0.CO

[3]

2-3

[4]

Drent E., 2000, A Polymerization Process. WO, Patent No. [00/06615, 0006615]

[5]

Drent E. P., 1994, EP Application, Patent No. [0,589,527, 0589527, 589527]

[6] Functionalised polyolefin synthesis using [P,O]Ni catalysts [J].

Gibson, VC ;

Tomov, A .

CHEMICAL COMMUNICATIONS, 2001, (19) :1964-1965

[7] Copolymerization of ethylene and propylene with functionalized vinyl monomers by palladium(II) catalysts [J].

Johnson, LK ;

Mecking, S ;

Brookhart, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (01) :267-268

[8] NOVEL COORDINATION OF (BENZOYLMETHYLENE)TRIPHENYLPHOSPHORANE IN A NICKEL OLIGOMERIZATION CATALYST [J].

KEIM, W ;

KOWALDT, FH ;

GODDARD, R ;

KRUGER, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (06) :466-467

[9] NICKEL CATALYSIS FOR ETHYLENE HOMOPOLYMERIZATION AND CO-POLYMERIZATION [J].

KLABUNDE, U ;

ITTEL, SD .

JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2) :123-134

[10] Copper-mediated controlled copolymerization of methyl acrylate with 1-Alkenes under mild conditions [J].

Liu, SH ;

Elyashiv, S ;

Sen, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (50) :12738-12739

← 1 2 →