Synthesis of a series of novel binucleating ligands based on 1,4,7-triazacyclononane and o-, m- and p-xylene: Crystal structure of the mu-hydroxy-bridged dicopper(II) complex [Cu(2)L(m)(OH)(2)][BPh(4)](2) [L(m) equals alpha,alpha'-bis(N-1,4,7-triazacyclononane)-m-xylene]

被引:48
作者
Farrugia, LJ [1 ]
Lovatt, PA [1 ]
Peacock, RD [1 ]
机构
[1] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,LANARK,SCOTLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 06期
关键词
D O I
10.1039/a608058h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structure and magnetic properties of [Cu(2)L(m)(OH)(2)][BPh(4)](2) has been determined; L(m) is one of three new binucleating ligands based on 1,4,7-triazacyclononane and o-, m- or p-xylene.
引用
收藏
页码:911 / 912
页数:2
相关论文
共 9 条
[1]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[2]  
[Anonymous], 1993, BIOINORGANIC CHEM CO
[3]   TRICYCLIC TRIS-AMINOMETHANES [J].
ATKINS, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (20) :6364-6365
[4]   PREPARATION, MAGNETISM, AND CRYSTAL-STRUCTURES OF THE TAUTOMERS [LCU(MU-2-OH)2CUL](CLO4)2(BLUE) AND [LCU(MU-2-OH2)(MU-2-O)CUL](CLO4)2(GREEN) - MU-AQUA-MU-OXO VS DI-MU-HYDROXO LINKAGE [J].
CHAUDHURI, P ;
VENTUR, D ;
WIEGHARDT, K ;
PETERS, EM ;
PETERS, K ;
SIMON, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (01) :57-59
[5]   Macrocycles with a single pendant arm: Synthesis of N-R-(1,4,7-triazacyclononane) [L,R=4-but-1-ene; L'=3-prop-1-ene]: Synthesis of the Cu-I complex [CuL]I and synthesis and crystals structure of the Cu-II complex [CuL(2)][BPh(4)]2 and the mu-hydroxy bridged Cu-II dimer [LCu(mu-OH)(2)CuL][BPh(4)](2) [J].
Farrugia, LJ ;
Lovatt, PA ;
Peacock, RD .
INORGANICA CHIMICA ACTA, 1996, 246 (1-2) :343-348
[6]  
FARRUGIA LJ, UNPUB
[7]  
Kahn O., 1993, MOL MAGNETISM
[8]   FUNCTIONAL-GROUP CONVERGENCE IN A BINUCLEAR DEPHOSPHORYLATION REAGENT [J].
VANCE, DH ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :12165-12166
[9]   DINUCLEAR COPPER(II) COMPLEX THAT HYDROLYZES RNA [J].
YOUNG, MJ ;
CHIN, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (42) :10577-10578