Simple preparation of nitroso benzenes and nitro benzenes by oxidation of anilines with H2O2 catalysed with molybdenum salts

被引：58

作者：

Defoin, A ^{[1
]}

机构：

[1] Univ Haute Alsace, Ecole Natl Super Chim Mulhouse, Lab Chim Organ & Bioorgan, UMR 7015, F-68093 Mulhouse, France

来源：

SYNTHESIS-STUTTGART | 2004年 / 05期

关键词：

nitroso arenes; nitro arenes; oxidation; molybdenum salts;

D O I：

10.1055/s-2004-815964

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitroso arenes 2a-k are prepared in 53-80% yield from anilines 1a-k by oxidation with H2O2 catalysed with MoO3/KOH, ammonium molybdate or other molybdenum salts. Further oxidation to nitro arenes 3a,d,j in 66-90% is also described.

引用

页码：706 / 710

页数：5

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