Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent

被引：59

作者：

Karlin, KD ^{[1
]}

Lee, DH ^{[1
]}

Kaderli, S ^{[1
]}

Zuberbuhler, AD ^{[1
]}

机构：

[1] UNIV BASEL,INST INORGAN CHEM,CH-4056 BASEL,SWITZERLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 05期

关键词：

HEMOCYANIN; KINETICS; ADDUCTS; O2;

D O I：

10.1039/a607862a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Entropic destabilization of low-molecular mass mu-peroxodicopper(II) complexes are overcome using a new binucleating open-chain ligand by the combination of an optimized linking unit with a less competing solvent; complete formation and satisfactory stability at room temperature are thus obtained.

引用

页码：475 / 476

页数：2

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