Kinetics of capillary condensation in a nanoscale pore

被引：92

作者：

Kohonen, MM ^{[1
]}

Maeda, N ^{[1
]}

Christenson, HK ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Dept Math Appl, Canberra, ACT 0200, Australia

来源：

PHYSICAL REVIEW LETTERS | 1999年 / 82卷 / 23期

关键词：

D O I：

10.1103/PhysRevLett.82.4667

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The rate of growth of capillary condensates in a model wedgelike pore has been studied using the surface force apparatus. The method described allows the direct measurement of the diffusion-limited growth of liquid condensates with interface radii of curvature as small as 20 nm. The observed rates of condensation of vapors of n-pentane, n-hexane, cyclohexane, and water are close to, but consistently lower than, values calculated from a model based on Langmuir's theory of droplet growth. [S0031-9007(99)09289-3].

引用

页码：4667 / 4670

页数：4

共 25 条

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