An allosterically regulated molecular shuttle.

被引：60

作者：

Marlin, DS

Cabrera, DG

Leigh, DA ^{[1
]}

Slawin, AMZ

机构：

[1] Univ Edinburgh, Sch Chem, Kings Bldg,W Mains Rd, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 09期

关键词：

allosterism; hydrogen bonds; molecular devices; rotaxanes; transition metals;

D O I：

10.1002/anie.200502624

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) When push comes to shove: A switchable [2]rotaxane has been developed in which the binding of a metal ion (e.g. Cd2+, see scheme) to a bis(picolyl)amine fragment that acts as one of the stoppers induces a shift of the macrocyclic component along the thread from one binding site (green) to another weaker binding site (orange). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1385 / 1390

页数：6

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