The use of AC potentials in electrospraying and electrospinning processes

被引:146
作者
Kessick, R
Fenn, J
Tepper, G
机构
[1] Virginia Commonwealth Univ, Dept Chem Engn, Richmond, VA 23284 USA
[2] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
关键词
electrospinning; electrospraying; fibers;
D O I
10.1016/j.polymer.2004.02.056
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The use of AC potentials in electrospraying and electrospinning processes was demonstrated. Carboxymethylcellulose (CMC) was electrosprayed onto semiconducting and insulating substrates using both DC and AC potentials. On the semiconducting substrate, both AC and DC methods were capable of producing significant CMC coverage. However, only the AC potential was capable of producing significant coverage on the insulating substrate, possibly due to a reduction in the amount of surface charging. In the electrospinning investigation, poly(ethylene oxide) (PEO) fibers were spun into mats using both DC and AC driving potentials. The AC potential resulted in a significant reduction in the amount of fiber 'whipping' and the resulting mats exhibited a higher degree of fiber alignment but were observed to contain more residual solvent. The average fiber diameter for both DC and AC-spun mats exhibited a strong dependence on solution concentration. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2981 / 2984
页数:4
相关论文
共 17 条
[1]   Controlled deposition of electrospun poly(ethylene oxide) fibers [J].
Deitzel, JM ;
Kleinmeyer, JD ;
Hirvonen, JK ;
Tan, NCB .
POLYMER, 2001, 42 (19) :8163-8170
[2]   Controlled deposition of electrospun poly(ethylene oxide) fibers [J].
Deitzel, JM ;
Kleinmeyer, JD ;
Hirvonen, JK ;
Tan, NCB .
POLYMER, 2001, 42 (19) :8163-8170
[3]   MOLECULAR BEAMS OF MACROIONS [J].
DOLE, M ;
MACK, LL ;
HINES, RL .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (05) :2240-&
[4]   ELECTROSPRAY IONIZATION FOR MASS-SPECTROMETRY OF LARGE BIOMOLECULES [J].
FENN, JB ;
MANN, M ;
MENG, CK ;
WONG, SF ;
WHITEHOUSE, CM .
SCIENCE, 1989, 246 (4926) :64-71
[5]   Generation of electrospun fibers of nylon 6 and nylon 6-montmorillonite nanocomposite [J].
Fong, H ;
Liu, WD ;
Wang, CS ;
Vaia, RA .
POLYMER, 2002, 43 (03) :775-780
[6]   VISUALIZATION OF AERODYNAMICALLY FOCUSED SUBSONIC AEROSOL JETS [J].
FUERSTENAU, S ;
GOMEZ, A ;
DELAMORA, JF .
JOURNAL OF AEROSOL SCIENCE, 1994, 25 (01) :165-173
[7]   Electrospray as a source of nanoparticles for efficient colloid thrusters [J].
Gamero-Castaño, M ;
Hruby, V .
JOURNAL OF PROPULSION AND POWER, 2001, 17 (05) :977-987
[8]   Electrostatic spraying: A novel technique for preparation of polymer coatings on electrodes [J].
Hoyer, B ;
Sorensen, G ;
Jensen, N ;
Nielsen, DB ;
Larsen, B .
ANALYTICAL CHEMISTRY, 1996, 68 (21) :3840-3844
[9]   On the evaporation of small ions from charged droplets [J].
IRIBARNE, JV ;
THOMSON, BA .
JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (06) :2287-2294
[10]   Release of tetracycline hydrochloride from electrospun poly(ethylene-co-vinylacetate), poly(lactic acid), and a blend [J].
Kenawy, ER ;
Bowlin, GL ;
Mansfield, K ;
Layman, J ;
Simpson, DG ;
Sanders, EH ;
Wnek, GE .
JOURNAL OF CONTROLLED RELEASE, 2002, 81 (1-2) :57-64