Synthesis and characterization of poly (aniline-co-acrylonitrile) using organic benzoyl peroxide by inverted emulsion method

被引：82

作者：

Jeevananda, T

Siddaramaiah ^{[1
]}

Seetharamu, S

Saravanan, S

D'Souza, L

机构：

[1] SJ Coll Engn, Dept Polymer Sci & Technol, Mysore 570006, Karnataka, India

[2] E Point Coll Engn & Technol, Dept Chem, Bangalore 560049, Karnataka, India

[3] Cent Power Res Inst, Bangalore 5600080, Karnataka, India

[4] Paul Scherrer Inst, Lab Solar Chem & Phys, CH-5232 Villigen, Switzerland

来源：

SYNTHETIC METALS | 2004年 / 140卷 / 2-3期

关键词：

polyaniline; copolymers; benzoyl peroxide; conductivity; spectroscopy;

D O I：

10.1016/S0379-6779(03)00366-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An inverted emulsion process was adopted to synthesize conducting copolymers of aniline and acrylonitrile using benzoyl peroxide (BPO) as a novel oxidizing agent. The influence of polyacrylonitrile (PAN) ratio on the properties of conducting copolymers is reported. The chemical structures of the copolymers were characterized spectroscopically by UV-Vis, FT-IR, Fr-Raman and EPR. The solubility of polyaniline (PAni) and PAni-PAN copolymers in dimethyl sulphoxide (DMSO) was confirmed by electronic absorption spectra. The conductivity of these copolymers he in the range (1.26-4.20) x 10(-2) S/cm. TGA thermogram, of copolymers showed multi-step thermal degradation behaviour. X-ray scattering studies reflected that the copolymers are semicrystalline and showed two crystalline peaks at 17 and 25 (2theta). (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：247 / 260

页数：14

共 51 条

[1] VARIABLE-TEMPERATURE EPR AND TRANSPORT STUDIES ON POLY(4,4'-METHYLENEDIANILINE) - EVIDENCE FOR BIPOLARONS [J].