Aqueous/ionic liquid interfacial polymerization for preparing polyaniline nanoparticles

被引:179
作者
Gao, HX [1 ]
Jiang, T [1 ]
Han, BX [1 ]
Wang, Y [1 ]
Du, JM [1 ]
Liu, ZM [1 ]
Zhang, JL [1 ]
机构
[1] Chinese Acad Sci, Ctr Mol Sci, Joint Lab Polymer Sci & Mat, Inst Chem,Grp 3, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
ionic liquid; interfacial polymerization; polyaniline;
D O I
10.1016/j.polymer.2004.03.002
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The interfacial polymerization of aniline at aqueous/IL has been conducted. The product was characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-vis spectroscopy, thermal gravimetric analysis (GTA), and electrical conductivity measurement. In this route, both solvents used are environmentally benign and polyaniline (PANI) particles with diameters from about 30-80 nm can be fabricated. We believe that this method can be used to synthesize some other useful polymers. ((C))2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3017 / 3019
页数:3
相关论文
共 43 条
[1]   Some novel liquid partitioning systems: Water-ionic liquids and aqueous biphasic systems [J].
Abraham, MH ;
Zissimos, AM ;
Huddleston, JG ;
Willauer, HD ;
Rogers, RD ;
Acree, WE .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (03) :413-418
[2]   AQUEOUS COLLOIDAL DISPERSIONS OF POLYANILINE FORMED BY USING POLY(VINYLPYRIDINE)-BASED STERIC STABILIZERS [J].
ARMES, SP ;
ALDISSI, M ;
AGNEW, S ;
GOTTESFELD, S .
LANGMUIR, 1990, 6 (12) :1745-1749
[3]   NOVEL COLLOIDAL DISPERSIONS OF POLYANILINE [J].
ARMES, SP ;
ALDISSI, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) :88-89
[5]  
Ashgarian B, 1999, MACROMOLECULES, V32, P5575
[6]   Studies on chemically synthesized soluble acrylic acid doped polyaniline [J].
Athawale, AA ;
Kulkarni, MV ;
Chabukswar, VV .
MATERIALS CHEMISTRY AND PHYSICS, 2002, 73 (01) :106-110
[7]  
BEESTMAN G B, 1983, Encapsulation by interfacial polycondensation: US, Patent No. [4417916, 4417916 [P]]
[8]  
Bösmann A, 2001, ANGEW CHEM INT EDIT, V40, P2697, DOI 10.1002/1521-3773(20010716)40:14<2697::AID-ANIE2697>3.0.CO
[9]  
2-W
[10]   Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide [J].
Brown, RA ;
Pollet, P ;
McKoon, E ;
Eckert, CA ;
Liotta, CL ;
Jessop, PG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (06) :1254-1255