A novel copper containing photoinitiator, copper(II) acylphosphinate, and its application in both the photomediated CuAAC reaction and in atom transfer radical polymerization

被引：68

作者：

Gong, Tao ^{[1
]}

Adzima, Brian J. ^{[1
]}

Bowman, Christopher N. ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 72期

基金：

美国国家科学基金会;

关键词：

AZIDE-ALKYNE CYCLOADDITION; TERMINAL ALKYNES; CLICK CHEMISTRY; LIGHT; PHOTOPOLYMERIZATION; OXIDE; ATRP;

D O I：

10.1039/c3cc43637c

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A novel copper(II) complex has been developed in which the counter anion, acylphosphinate, serves as a visible light photoinitiator. This molecule is inactive in the dark but, upon visible light exposure, both CuAAC and ATRP reactions are readily and rapidly initiated.

引用

页码：7950 / 7952

页数：3

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