Speciation of antimony by adsorptive stripping voltammetry using pyrogallol red

被引：18

作者：

Gomez Gonzalez, M. Jesus ^{[1
]}

Dominguez Renedo, Olga ^{[1
]}

Arcos Martinez, M. Julia ^{[1
]}

机构：

[1] Univ Burgos, Fac Ciencias, Area Quim Analit, Dept Quim, E-09001 Burgos, Spain

来源：

ELECTROANALYSIS | 2006年 / 18卷 / 12期

关键词：

speciation; antimony; stripping voltammetry; multivariate calibration;

D O I：

10.1002/elan.200603515

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This paper proposes a procedure for the speciation of antimony by Differential Pulse Adsorptive Stripping Voltammetry (DPAdSV) using pyrogallol red (PGR) as a complexing agent. It employs a Partial Least Squares regression (PLS) in the resolution of strongly overlapping voltammetric signals obtained from mixtures of Sb(III) and Sb(V) in the presence of pyrogallol red. The absolute value of the relative error was less than 3.5% when concentrations of several mixtures were calculated, the minimum concentrations being 9.98 x 10(-9) mol dm(-3) and 4.87 x 10(-8) mol dm(-3) for Sb(III) and Sb(V), respectively. Any undue effects caused by the presence of foreign ions in the solution were also analyzed. The procedure was successfully applied to the speciation of antimony in pharmaceutical preparations.

引用

页码：1159 / 1166

页数：8

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