Synthesis, X-ray and solid state NMR studies on silver(I) silanethiolates.: Crystal structure of bis[(triphenylphosphine)-(tri-o-tolylsilanethiolato)silver(I)]-toluene(1/2), [{Ag[SSi(C6H4-Me-o)3](PPh3)}2]•2C6H5Me

被引：25

作者：

Chojnacki, J

Becker, B

Konitz, A

Potrzebowski, MJ

Wojnowski, W

机构：

[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland

[2] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a903694f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of silver(I) trialkoxysilanethiolates [Ag(SSiR3)(PPh3)(2)], R = (BuO)-O-t, (BuO)-O-s or (PrO)-O-i, and triarylsilanethiolates [Ag(SSiR'(3))(PPh3)], R' = o-MeC6H4 or Ph, were obtained by reaction of [Ag(acac)(PPh3)(2)] with the respective silanethiols. Products were studied by H-1 NMR, CP MAS P-31 and Si-29 NMR in solution and/or in the solid state. A single-crystal X-ray structural analysis was carried on for [{Ag[SSi(C6H4Me-o)(3)](PPh3)}(2)]. 2C(6)H(5)Me.

引用

页码：3063 / 3068

页数：6

共 28 条

[1] Silver(I)-silver(I) interactions in the tetrameric silver thiolate phosphine complex [Ag4(SPh)4(PPh3)4]
Ahmed, LS
Dilworth, JR
Miller, JR
Wheatley, N
[J]. INORGANICA CHIMICA ACTA, 1998, 278 (02) : 229 - 231
[2] Synthesis and characterization of [Ag4(μ3-SC2B10H11)2(μ-O3SCF3)2(PPh3)4]:: A silver complex with a μ3-thiolate ligand
Artigas, MM
Crespo, O
Gimeno, MC
Jones, PG
Laguna, A
Villacampa, MD
[J]. INORGANIC CHEMISTRY, 1997, 36 (27) : 6454 - 6456
[3] Silver(I) complexes with heterocyclic thiones and tertiary phosphines as ligands .2. Mononuclear complexes of silver(I) nitrate. The crystal structures of [Ag(PPh(3))(2)(pytH)(2)]NO3 and [Ag(PPh(3))(2)(pymtH)]NO3
Aslanidis, P
Karagiannidis, P
Akrivos, PD
Krebs, B
Lage, M
[J]. INORGANICA CHIMICA ACTA, 1997, 254 (02) : 277 - 284
[4] PHOSPHOLE COMPLEXES OF SILVER(I) - INVESTIGATIONS OF STRUCTURE AND BONDING BY X-RAY CRYSTALLOGRAPHY, INFRARED-SPECTROSCOPY, AND CP/MAS AND SOLUTION P-31 NMR-SPECTROSCOPY
ATTAR, S
ALCOCK, NW
BOWMAKER, GA
FRYE, JS
BEARDEN, WH
NELSON, JH
[J]. INORGANIC CHEMISTRY, 1991, 30 (22) : 4166 - 4176
[5] CHEMISTRY OF SILICON-SULFUR COMPOUNDS .64. CRYSTAL AND MOLECULAR-STRUCTURE OF (TRI-TERT-BUTOXYSILANETHIOLATO)BIS(TRIPHENYL-PHOSPHINE)COPPER(I) (T-C4H9O)3SISCU[P(C6H5)3]2
BECKER, B
WOJNOWSKI, W
PETERS, K
PETERS, EM
[J]. INORGANICA CHIMICA ACTA, 1993, 214 (1-2) : 9 - 11
[6] Zinc silanethiolates: Synthesis and properties. Crystal structures of bis(tri-tert-butoxysilanethiolato)(acetonitrile)zinc(II) and bis(tri-tert-butoxysilanethiolato)(bipyridine)zinc(II)
Becker, B
Radacki, K
Wojnowski, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 521 (1-2) : 39 - 49
[7] CONTRIBUTIONS TO THE CHEMISTRY OF SILICON SULFUR-COMPOUNDS .24. SPECTROPHOTOMETRIC INVESTIGATIONS OF ACIDITY OF SILANETHIOLS AND QUANTITATIVE RELATIONSHIPS BETWEEN THE STRUCTURE AND DELTA-BAR-NU(SH), HNP, AND PK VALUES
BECKER, B
FELCYN, EW
HERMAN, A
PIKIES, J
WOJNOWSKI, W
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 488 (05): : 229 - 234
[8] CONTRIBUTIONS TO THE CHEMISTRY OF SILICON SULFUR-COMPOUNDS .27. THE INSERTION OF SULFUR INTO THE SILICON HYDROGEN-BOND OF ARYLSILANES - THE PREPARATION OF ARYLSILANETHIOLS AND ARYLDISILTHIANES
BECKER, B
WOJNOWSKI, W
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1982, 12 (05): : 565 - 582
[9] CONTRIBUTIONS TO THE CHEMISTRY OF SILICON SULFUR-COMPOUNDS .57. SYNTHESIS, MOLECULAR-STRUCTURE AND PROPERTIES OF CYCLO-TETRAKIS-[TRI-TERT-BUTOXYSILANETHIOLATOCOPPER(I)], [(T-C4H9O)3SISCU]4, THE 1ST EXAMPLE OF A SQUARE-PLANAR CU4S4 RING
BECKER, B
WOJNOWSKI, W
PETERS, K
PETERS, EM
VONSCHNERING, HG
[J]. POLYHEDRON, 1990, 9 (14) : 1659 - 1666
[10] Becker B, 1998, Z KRIST-NEW CRYST ST, V213, P697

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