Synthesis of new fluorescent 2-(2′,2"-bithienyl)-1,3-benzothiazoles

被引:99
作者
Batista, RMF [1 ]
Costa, SPG [1 ]
Raposo, MMM [1 ]
机构
[1] Univ Minho, Ctr Quim, P-4710057 Braga, Portugal
关键词
fluorescence; solvatochromism; 5-formyl-5 '-alkoxy-2,2 '-bithiophenes; 5-formyl-5 '-N,N-dialkylamino-2,2 '-bithiophenes 1,3-benzothiazoles; 2-(2 ',2 ''-bithienyl)-1,3-benzothiazoles;
D O I
10.1016/j.tetlet.2004.02.048
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Bithienyl-1,3-benzothiazole derivatives were synthesised by reacting various 5-formyl-5'-alkoxy- or 5-formyl-5'-N,N-dialkylamino-2,2'-bithiophenes with ortho-aminobenzenethiol in good to excellent yields. Evaluation of the fluorescence properties of these compounds was carried out. They Show strong fluorescence in the 450-600 nm region, as well as high quantum yields and large Stokes' shifts. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2825 / 2828
页数:4
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