Asymmetric alkylidenecyclopropanes from the regioselective reduction of pi 1,1-dimethyleneallyl palladium complexes

被引：22

作者：

Chevtchouk, T ^{[1
]}

Ollivier, J ^{[1
]}

Salaun, J ^{[1
]}

机构：

[1] UNIV PARIS 11, INST CHIM MOL, ASSOC CNRS, LAB CARBOCYCLES, F-91405 ORSAY, FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(97)00076-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(0) catalyzed hydrogenolysis of (1R,2S)-1-(1-alkenyl)-2-methylcyclopropyl mesylate 6b led to (E)-(2S)-alkenylidene(2-methylcyclopropanes), regioselectively, depending on the steric effect of trivalent phosphorus palladium ligands. (C) 1997 Elsevier Science Ltd.

引用

页码：1005 / 1009

页数：5

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