Energetic materials: The biguanidium nitrates

被引：15

作者：

Martin, A

Pinkerton, AA

Schiemann, N

机构：

[1] Department of Chemistry, University of Toledo, Toledo

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195012200

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of two new potentially energetic biguanidium salts, biguanidium nitrate, C2H8N5+.NO3- [(BIGH)NO3], and biguanidium dinitrate, C2H9N52+.-2NO(3)(-) [(BIGH(2))(NO3)(2)], have been determined from X-ray data collected at 193 K. The mono- and diprotonated biguanidium nitrates are dense organic materials with efficient packing of planar anions and biplanar (twisted) cations connected by multiple hydrogen bonds. The experimental densities are compared with those obtained from empirical calculations.

引用

页码：966 / 970

页数：5

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