An octanuclear [Co(II)2-Co(II)2]2 interlocked grid -: example of an inorganic [2]catenane

被引:49
作者
Abedin, TSM [1 ]
Thompson, LK [1 ]
Miller, DO [1 ]
机构
[1] Mem Univ St Johns, Dept Chem, St John, NF A1B 3X7, Canada
关键词
D O I
10.1039/b510755e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An oxalic dihydrazide based flexible polydentate amidrazone ligand undergoes spontaneous [2 x 2] grid assembly, followed by partial disassembly, and then reassembly in the presence of Co(NO3)(2)(.)6H(2)O and NH4(NCS) to form a unique octanuclear [Co(II)(2)-Co(III)(2)](2) interlocked, single braided 4 + 4 [2]catenane.
引用
收藏
页码:5512 / 5514
页数:3
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