Syntheses of a new segmental penta-heterocyclic ligand and its dinuclear ruthenium(II) complex

被引：11

作者：

Phillips, IG ^{[1
]}

Steel, PJ ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

INORGANICA CHIMICA ACTA | 1996年 / 244卷 / 01期

关键词：

ruthenium complexes; pyridine complexes; pyrimidine complexes; dinuclear complexes;

D O I：

10.1016/0020-1693(96)04997-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ligand 2,6-bis-[6-(2-pyridinyl)-4-pyrimidinyl]pyridine (2) has been synthesised, in two steps, by a double Claisen condensation, followed by cyclisation with formation of the two pyrimidine rings. The ligand forms a dinuclear ruthenium(II) complex, with coordination through the two terminal bpy-like components, which has been characterised by spectroscopic and electrochemical methods.

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页码：3 / 5

页数：3

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